The first conducting cationic bis-dithiolene complexes of nickel and gold

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2158–2159, September, 1989.     

Cross-relaxation effects in the luminescence of erbium at 1.5 μm

Journal of Applied Spectroscopy -     

Multiphoton excitation and dissociation of CH3OH molecules by intense broadband YSGG:Cr:Er laser radiation in the range 2.7 µm

We have observed efficient multiphoton excitation of CH₃OH molecules by broadband pulsed YSGG:Cr:Er-laser radiation (λ=2.7 µm,τ _p =60 ns, and Δν_las～1.5 cm^?1) at fluences of 0.3-600 J/cm² under collisional and collisionless conditions. Multiphoton dissociation of CH₃OH has been realized. We discuss the role of intermode interaction, the intensity of the laser radiation, and the laser bandwidth in the excitation process.     

Quasi-free scattering in 7(p,pd)5He and 12C(p,pd)10B reactions at 670 MeV

The reactions ⁷Li(p, pd)⁵He and ¹²C(p, pd)¹⁰ were investigated at 670 MeV in quasi-free scattering geometry at large angles. In transitions to low-lying as well as to highly excited states of the residual nuclei the energy distributions of the scattered protons are in agreement with the mechanism of quasi-free scattering on quasi-deuterons in the p- and s-shells of ⁷Li and ¹²C.     

An efficient procedure for the synthesis of Esomeprazole using a titanium complex with two chiral ligands

A procedure has been proposed for the selective preparation of Esomeprazole via asymmetric oxidation of the corresponding prochiral sulfide in the presence of a catalytic complex derived from titanium(IV) isopropoxide and two different chiral ligands, diethyl d-tartrate and (R)-N,N-dimethyl-1-phenyl-ethanamine.     

Numerical investigation of the microstructure of a clad layer produced via laser cladding with coaxial metal powder injection

The microstructure of a clad layer produced via selective laser cladding with coaxial metal powder injection is studied numerically. The Johnson–Mehl–Avrami–Kolmogorov equation for condensed systems with inhomogeneous rates of nucleation is used to model the phase change kinetics. The impact of the substrate boundary along with interconnected heat transfer and phase change processes on the final microstructure of a built-up layer is demonstrated. The qualitative difference between the behavior of the temperature on the built-up layer’s surface and at the depth of the substrate is established, revealing the inhomogeneous microstructure of the final layer.